Anodic Oxidation Enabled Cation Leaching for Promoting Surface Reconstruction in Water Oxidation
نویسندگان
چکیده
A rational design for oxygen evolution reaction (OER) catalysts is pivotal to the overall efficiency of water electrolysis. Much work has been devoted understanding cation leaching and surface reconstruction very active electrocatalysts, but little on intentionally promoting in a controlled fashion. We now report controllable anodic Cr CoCr2O4 by activating pristine material at high potential, which enables transformation inactive spinel into highly catalyst. The depletion consumption lattice facilitate defects vacancies, exposing Co species reconstruct oxyhydroxides differ from CoOOH. novel mechanism with tetrahedrally coordinated octahedral configuration via non-concerted proton-electron transfer proposed. This shows importance potential modifying chemistry electrocatalysts.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202015060